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Tritellurium dichloride
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Tritellurium dichloride : ウィキペディア英語版
Tritellurium dichloride

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Tritellurium dichloride is the inorganic compound with the formula Te3Cl2. It is one of the more stable lower chlorides of tellurium.
==Preparation and properties==
Te3Cl2 is a gray solid. Its structure consists of a long chain of Te atoms, with every third Te center carrying two chloride ligands for the repeat unit -Te-Te-TeCl2-. It is a semiconductor with a band gap of 1.52 eV, which is larger than that for elemental Te (0.34 eV).〔 It is prepared by heating Te with the appropriate stoichiometry of chlorine.〔R. Kniep, D. Mootz, A. Rabenau "Zur Kenntnis der Subhalogenide des Tellurs" Zeitschrift für anorganische und allgemeine Chemie 1976, Volume 422, pages 17–38. 〕

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